Investigation Of Lini_(1/3)co_(1/3)mn_(1/3)o_2 Cathode Particles After 300 discharge/charge Cycling In A Lithium-ion battery By Analytical Tem

摘要

Using analytical transmission electron microscopy (TEM) techniques reveal a zigzag layer on surface of the cycled particles of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 cathode after 300 discharge/charge cycles. The Ni, Mn content in the zigzag layer of the cycled particle has decreased rapidly from interior to edge of the zigzag layer of the cycled particles. The structure of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 oxide was gradually destructed from hexagonal cell with P3_1 12 at interior region to fec lattice of α-NaFeO_2 at edge of the zigzag layer of the cycled particles. These experimental data provide the compositional and structural origins of the capacity decrease in the Li-ion battery.