Improved electrolytes for Li-ion batteries: Mixtures of ionic liquid and organic electrolyte with enhanced safety and electrochemical performance

摘要

Physical and electrochemical characteristics of Li-ion battery systems based on LiFePO_4 cathodes and graphite anodes with mixture electrolytes were investigated. The mixed electrolytes are based on an ionic liquid (IL), and organic solvents used in commercial batteries. We investigated a range of compositions to determine an optimum conductivity and non-flammability of the mixed electrolyte. This led us to examine mixtures of ILs with the organic electrolyte usually employed in commercial Li-ion batteries, i.e., ethylene carbonate (EC) and diethylene carbonate (DEC). The IL electrolyte consisted of (trifluoromethyl sulfonylimide) (TFS1) as anion and 1 -ethyl-3-methyleimidazolium (EMI) as the cation. The physical and electrochemical properties of some of these mixtures showed an improvement characteristics compared to the constituents alone. The safety was improved with electrolyte mixtures; when IL content in the mixture is >40%, no flammability is observed. A stable SE1 layer was obtained on the MCMB graphite anode in these mixed electrolytes, which is not obtained with IL containing the TFSI-anion. The high-rate capability of LiFePO_4 is similar in the organic electrolyte and the mixture with a composition of 1:1. The interface resistance of the LiFePO_4 cathode is stabilized when the ILis added to the electrolyte. A reversible capacity of 155 mAh g~(-1) at C/12 is obtained with cells having at least some organic electrolyte compared to only 124 mAh g~(-1) with pure IL. With increasing discharge rate, the capacity is maintained close to that in the organic solvent up to 2 C rate. At higher rates, the results with mixture electrolytes start to deviate from the pure organic electrolyte cell. The evaluation of the Li-ion cells; LiFePO_4//Li_4Ti_5O_(12) with organic and, 40% mixture electrolytes showed good 1st CE at 98.7 and 93.0%, respectively. The power performance of both cell configurations is comparable up to 2C rate. This study indicates that safety and electrochemical performance of the Li-ion battery can be improved by using mixed IL and organic solvents.