首页> 外文期刊>Journal of power sources >The influence of compositional change of 0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2 (0.2 ≤ x ≤0.5, y=x - 0.1) cathode materials prepared by co-precipitation
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The influence of compositional change of 0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2 (0.2 ≤ x ≤0.5, y=x - 0.1) cathode materials prepared by co-precipitation

机译:共沉淀制备的正极材料0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2(0.2≤x≤0.5,y = x-0.1)组成变化的影响

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摘要

Cathode materials prepared by a co-precipitation are 0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2 (0.2≤x≤0.4) cathode materials with a layered-spinel structure. In the voltage range of 2.0-4.6V, the cathodes show more than one redox reaction peak during its cyclic voltammogram. The Li/0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2 (x = 0.3, y = 0.2) cell shows the initial discharge capacity of about 200mAhg~(-1). However, when x=0.2 and y = 0.1, the cell exhibits a rapid decrease in discharge capacity and poor cycle life.
机译:通过共沉淀制备的阴极材料是具有层状尖晶石结构的0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2(0.2≤x≤0.4)阴极材料。在2.0-4.6V的电压范围内,阴极在其循环伏安图中显示多个氧化还原反应峰。 Li / 0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2(x = 0.3,y = 0.2)电池的初始放电容量约为200mAhg〜(-1)。然而,当x = 0.2且y = 0.1时,电池表现出放电容量的迅速降低和较差的循环寿命。

著录项

  • 来源
    《Journal of power sources》 |2011年第7期|p.3439-3442|共4页
  • 作者单位

    Battery Piezoelectric Research Center, Korea Electrotechnology Research Institute, 28-1, Seongju-dong, Changwon, Gyeongsangnam-do 641-120, Republic of Korea;

    Battery Piezoelectric Research Center, Korea Electrotechnology Research Institute, 28-1, Seongju-dong, Changwon, Gyeongsangnam-do 641-120, Republic of Korea;

    Daejung EM Co., Incheon 405-820, Republic of Korea;

    School of Mechanical, Materials and Mechatronic Engineering, University ofWollongong, NSW 2522, Australia;

    Battery Piezoelectric Research Center, Korea Electrotechnology Research Institute, 28-1, Seongju-dong, Changwon, Gyeongsangnam-do 641-120, Republic of Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    lithium ion batteries; 0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2; Co-precipitation;

    机译:锂离子电池;0.3Li_2MnO_3·0.7LiMn_(1-x)Ni_yCo_(0.1)O_2;共沉淀;

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