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首页> 外文期刊>Journal of Polymers and the Environment >Study on the Physico-mechanical Properties of Photo-cured Chitosan Films with Oligomer and Acrylate Monomer
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Study on the Physico-mechanical Properties of Photo-cured Chitosan Films with Oligomer and Acrylate Monomer

机译:低聚物和丙烯酸酯单体光固化壳聚糖薄膜的物理力学性能研究

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摘要

Chitosan films were prepared from dried prawn shell via chitin and then tensile properties like tensile strength (TS) and elongation at break (Eb) of the films were evaluated. Six formulations were developed using methyl methacylate (MMA) monomer and aliphatic urethane diacrylate oligomer (M-1200) in methanol along with photoinitator (Darocur-1664). Then the films were soaked in the formulations and irradiated under UV radiation at different doses for the improvement of physico-mechanical properties of chitosan films. The cured films were characterized by measuring TS, Eb, polymer loading (PL), water absorption and gel content properties. The formulation containing 43% MMA and 15% oligomer in methanol solution showed the best performance at 20th UV pass for 4 min soaking time.
机译:从干燥的虾壳经甲壳质制备壳聚糖薄膜,然后评估薄膜的拉伸性能,如拉伸强度(TS)和断裂伸长率(Eb)。使用甲基丙烯酸甲酯(MMA)单体和脂肪族氨基甲酸酯二丙烯酸酯低聚物(M-1200)在甲醇中以及光引发剂(Darocur-1664)开发了六种配方。然后将膜浸入制剂中,并以不同剂量在紫外线辐射下辐照,以改善壳聚糖膜的物理机械性能。通过测量TS,Eb,聚合物负载量(PL),吸水率和凝胶含量特性来表征固化膜。在甲醇溶液中包含43%MMA和15%低聚物的配方在第20次紫外线通过4分钟的浸泡时间内显示出最佳性能。

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  • 来源
    《Journal of Polymers and the Environment》 |2008年第4期|213-219|共7页
  • 作者单位

    Department of Applied Chemistry and Chemical Technology, University of Rajshahi, Rajshahi, Bangladesh;

    Radiation and Polymer Chemistry Laboratory, Institute of Nuclear Science and Technology, Bangladesh Atomic Energy Commission, P.O. Box 3787, Dhaka 1000, Bangladesh;

    Radiation and Polymer Chemistry Laboratory, Institute of Nuclear Science and Technology, Bangladesh Atomic Energy Commission, P.O. Box 3787, Dhaka 1000, Bangladesh;

    Department of Applied Chemistry and Chemical Technology, University of Dhaka, Dhaka 1000, Bangladesh;

    Department of Applied Chemistry and Chemical Technology, University of Rajshahi, Rajshahi, Bangladesh;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    chitosan; UV-radiation; photo-curing; methyl methacylate; biodegradable;

    机译:壳聚糖紫外线辐射;光固化;甲基丙烯酸甲酯;可生物降解;

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