New Polyacrylamide [PAM] Material Formulations for the Coagulation/Flocculation/Decantation Process

摘要

A new copolymers, high molecular weight poly(acrylamide) [AM2A0.01W20] and [AM1A0.1W20] were synthesized by radical adiabatic copolymerization in aqueous solution. The [AM2A0.01W20] copolymer was hydrolysed in basic medium by using sodium hydroxide solution and leads to a new hydrolysed poly(acrylamide) [AM3A0.01W20-H]. The structure and composition of the copolymers were established by H-1 NMR, IRTF and conductivity. The molecular weights are obtained by size exclusion chromatography [SEC] and by viscosity. The variation of the reduced viscosity of aqueous copolymer solutions with copolymer concentration revealed a strong viscosity values showing very high [PAM] molecular weights. In the present work, several copolymer formulations are tested by the process of Coagulation/Flocculation/Decantation with a Jar-test, using a 30 mg L-1 clay suspension. The optimization process shows that the copolymers present different flocculation efficiencies. The copolymers with the best performances were tested on a semi-industrial experimental pilot for the Coagulation/Flocculation/Decantation process. Good Flocculation yield superior than 70 % are observed for the [AM3A0.01W20-H] with high molecular weight.