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首页> 外文期刊>Journal of Hazardous Materials >Study of catalytic decomposition of formaldehyde on Pt/TiO_2 alumite catalyst at ambient temperature
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Study of catalytic decomposition of formaldehyde on Pt/TiO_2 alumite catalyst at ambient temperature

机译:Pt / TiO_2氧化铝催化剂在常温下催化分解甲醛的研究。

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摘要

Formaldehyde (HCHO) emitted from buildings, furnishing materials and consumer products is one of the most dominant volatile organic compounds (VOCs) in an indoor environment. In this work, a Pt/TiO_2/Al_2O_3 catalyst was prepared on an anodic alumite plate and was employed in the catalytic decomposition of formaldehyde at ambient temperature. Firstly, TiO_2 was deposited on the anodic alumite plate with electro-deposition technology. Then, platinum was supported on the anodic alumite plate with wet impregnation method. The developed catalyst exhibits good activity towards the decomposition of HCHO at ambient temperature. TPR (temperature programmed reduction) and TPD (temperature programmed desorption) analysis results indicate that oxygen adsorbed on the Pt/TiO_2/Al_2O_3 catalyst can be activated and generated to O:Pt_(surface) species quickly at ambient temperature. Hence, the developed catalyst experiences the high activity towards the catalytic decomposition of formaldehyde at ambient temperature.rnMoreover, in accordance with the process requirements, the developed catalyst can be formed into various shapes such as a mesh, plate, fin, serrate etc., because aluminum can be formed into any shapes. The serrate type catalyst was prepared in this work and it also exhibits fine activity towards the decomposition of HCHO.
机译:从建筑物,家具材料和消费品中排放的甲醛(HCHO)是室内环境中最主要的挥发性有机化合物(VOC)之一。在这项工作中,在阳极氧化铝板上制备了Pt / TiO_2 / Al_2O_3催化剂,并将其用于环境温度下的甲醛催化分解。首先,采用电沉积技术将TiO_2沉积在阳极氧化铝板上。然后,通过湿式浸渍法将铂负载在阳极氧化铝板上。所开发的催化剂在环境温度下对HCHO的分解表现出良好的活性。 TPR(程序升温还原)和TPD(程序升温脱附)分析结果表明,吸附在Pt / TiO_2 / Al_2O_3催化剂上的氧可以在环境温度下快速活化并生成O:Pt_(表面)物种。因此,开发的催化剂在室温下对甲醛的催化分解具有很高的活性。此外,根据工艺要求,可以将开发的催化剂制成各种形状,例如网眼,板状,鳍状,锯齿状等。因为铝可以制成任何形状。在这项工作中制备了锯齿状催化剂,并且对HCHO的分解也显示出优良的活性。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2009年第3期|399-405|共7页
  • 作者单位

    Kameyama & Sakurai Laboratory, Department of Chemical Engineering, Faculty of Engineering, Tokyo University of Agriculture and Technology, 24-16 Nakacho 2, Koganei-Shi, Tokyo 184-8588, Japan;

    Kameyama & Sakurai Laboratory, Department of Chemical Engineering, Faculty of Engineering, Tokyo University of Agriculture and Technology, 24-16 Nakacho 2, Koganei-Shi, Tokyo 184-8588, Japan;

    Kameyama & Sakurai Laboratory, Department of Chemical Engineering, Faculty of Engineering, Tokyo University of Agriculture and Technology, 24-16 Nakacho 2, Koganei-Shi, Tokyo 184-8588, Japan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    formaldehyde; Pt/TiO_2/Al_O_3; structured catalyst; anodic alumite film; TPD; TPR;

    机译:甲醛;Pt / TiO_2 / Al_O_3;结构催化剂阳极氧化铝膜TPD;TPR;

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