Defluoridation of synthetic and industrial wastewater by using acidic activated alumina adsorbent: characterization and optimization by response surface methodology

摘要

Excessive contamination of fluoride in wastewater is the cause of several chronic health problems. For this purpose, an adsorbent was prepared from alumina by acidic activation using sulfuric acid. The current research aims to find the maximum fluoride adsorption (%) from synthetic and industrial wastewater at optimum process parameters by using response surface methodology (RSM). All batch scale experiments were carried out according to the statistical-design order. Central composite design (CCD) was applied to ascertain the effect of adsorbent dose, pH, initial fluoride concentration and temperature on fluoride adsorption (%). Maximum fluoride removal was predicted based on the quadratic model developed. Validation of the model was done with negligible error. The regression coefficient of the model was found to be 0.96. From the analysis of variance (ANOVA), the factors with the greatest effect on the adsorption of fluoride were identified. Under optimized condition, the adsorbent dose 13.89 g L-1, pH 5.52, temperature 25 degrees C and initial fluoride concentration 18.67 mg L-1 resulted in 96% of maximum fluoride adsorption. Under the same optimized parameters, the fluoride adsorption from industrial wastewater found to be 92.10%.