Investigation of the vertical distribution and speciation of Cs-137 in soil profiles at burnt and unburnt forest sites in the Belarusian Exclusion Zone

摘要

The effects of fire events on contaminant radionuclides within soils of the Belarusian Exclusion Zone were investigated. A number of cores were taken from locations known to have been subject to fire events in the past as well as a series of cores from nearby unburnt locations. Both burnt and unburnt cores were analyzed for contaminant radionuclides as well as a range of relevant soil parameters. The distribution of Cs-137 between various fractions (reversibly bound, irreversibly bound and insoluble) was analyzed. Results indicate no evidence of enhancement or enrichment of radionuclides within the soil column although this does not negate the possibility that such effects were evident at some point in the past, the fire events at two of the sites having occurred almost ten years earlier. Evidence was present of a persistent effect on how Cs-137 was distributed between different fractions of the soil, primarily in relation to the proportions associated with oxides of Fe and Mn and organic matter. The results of the study appear to indicate that the long-term effects of a forest fire on contaminant Cs-137 within the soil column are expressed through changes in the physico-chemical forms of the nuclide to a larger extent than simple redistribution of the contaminant within the soil column. (C) 2017 Elsevier Ltd. All rights reserved.