The influence of the precursor and synthesis method on the CO_2 capture capacity of carpet waste-based sorbents

摘要

Adsorption is one of the most promising technologies for reducing CO_2 emissions and at present several different types of sorbents are being investigated. The use of sorbents obtained from low-cost and abundant precursors (i.e. solid wastes) appears an attractive strategy to adopt because it will contribute to a reduction not only in operational costs but also in the amount of waste that is dumped and burned in landfills every year. Following on from previous studies by the authors, in this work several carbon-based adsorbents were developed from different carpet wastes (pre-consumer and post-consumer wastes) by chemical activation with KOH at various activation temperatures (600—900 °C) and KOHxhar impregnation ratios (0.5:1 to 4:1). The prepared materials were characterised by chemical analysis and gas adsorption (N2, -196 °C; CO_2, 0 °C), and tested for CO2 adsorption at temperatures of 25 and 100 °C. It was found that both the type of precursor and the conditions of activation (i.e. impregnation ratios, and activation temperatures), had a huge influence on the microporosity of the resultant samples and their CO_2 capture capacities. The carbon-based adsorbent that presented the maximum CO_2 capture capacities at 25 and 100 °C (13.8 wt.% and 3.1 wt%, respectively), was prepared from a pre-consumer carpet waste and was activated at 700 °C using a KOHxhar impregnation ratio of 1:1. This sample showed the highest narrow microporosity volume (0.47 cm3 g~T), thus confirming that only pores of less than 1 nm are effective for CO2 adsorption at atmospheric pressure.%Department of Organic and Inorganic Chemistry, Faculty of Sciences, University of Extremadura, Avd. de Elvas s, E-06071 Badajoz, Spain ;Instituto National del Carbdn, CSIC, Apartado 73, 33080 Oviedo, Spain ;Instituto National del Carbdn, CSIC, Apartado 73, 33080 Oviedo, Spain ;Centre for Innovation in Carbon Capture and Storage (CICCS), Energy and Sustainability Research Division, Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom;Centre for Innovation in Carbon Capture and Storage (CICCS), Energy and Sustainability Research Division, Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, United Kingdom;