Transport of dissolved organic matter in Boom Clay: Size effects

摘要

AbstractA coupled experimental-modelling approach was developed to evaluate the effects of molecular weight (MW) of dissolved organic matter (DOM) on its transport through intact Boom Clay (BC) samples. Natural DOM was sampledin-situin the BC layer. Transport was investigated with percolation experiments on 1.5cm BC samples by measuring the outflow MW distribution (MWD) by size exclusion chromatography (SEC). A one-dimensional reactive transport model was developed to account for retardation, diffusion and entrapment (attachment and/or straining) of DOM. These parameters were determined along the MWD by implementing a discretisation of DOM into several MW points and modelling the breakthrough of each point. The pore throat diameter of BC was determined as 6.6–7.6nm. Below this critical size, transport of DOM is MW dependent and two major types of transport were identified. Below MW of 2kDa, DOM was neither strongly trapped nor strongly retarded. This fraction had an averaged capacity factor of 1.19±0.24 and an apparent dispersion coefficient ranging from 7.5×10−11to 1.7× 10−11m2/s with increasing MW. DOM with MW>2kDa was affected by both retardation and straining that increased significantly with increasing MW while apparent dispersion coefficients decreased. Values ranging from 1.36 to 19.6 were determined for the capacity factor and 3.2×10−11to 1.0×10−11m2/s for the apparent dispersion coefficient for species with 2.2kDaHighlights•Coupling of percolation experiments, size exclusion chromatography and reactive transport modelling•Pore throat diameter of Boom Clay estimated as 6.6-7.6 nm•Transport of DOM in Boom Clay is molecular weight dependent.•Small DOM species (< 2 kDa) are low-retarded and not strongly immobilised.•Retardation and straining of larger DOM species (2 kDa < MW < 25-32 kDa) increase with molecular weight.