Physicochemical factors and sources of particulate matter at residential urban environment in Kuala Lumpur

摘要

Long-term measurements (2004-2011) of PM_(10) (particulate matter with an aerodynamic diameter ＜10 μm) and trace gases (carbon monoxide [CO], ozone [O_3], nitrogen oxide [NO], oxides of nitrogen [NO_x], nitrogen dioxide [NO_2], sulfur dioxide [SO_2], methane [CH_4], nonmethane hydrocarbon [NMHC]) have been conducted to study the effect of physicochemical factors on the PM_(10) concentration. In addition, this study includes source apportionment of PM_(10) in Kuala Lumpur urban environment. An advanced principal component analysis (PCA) technique coupled with absolute principal component scores (APCS) and multiple linear regression (MLR) has been applied. The average annual concentration of PM_(10) for 8 yr is 51.3 ± 25.8 fig m~(-3), which exceeds the Recommended Malaysian Air Quality Guideline (RMAQG) and international guideline values. Detail analysis shows the dependency of PM_(10) on the linear changes of the motor vehicles in use and the amount of biomass burning, particularly from Sumatra, Indonesia, during southwesterly monsoon. The main sources of PM_(10) identified by PCA-APCS-MLR are traffic combustion (28%), ozone coupled with meteorological factors (20%), and windblown particles (1%). However, the apportionment procedure left 28.0 μg m~(-3), that is, 51% of PM_(10) undetermined. Implications: Air quality is always a top concern around the globe. Especially in the South Asian regions, measures are not yet sufficient; as revealed in our studies, the concentrations of particulate matters exceed the tolerable limits. Long-term data analysis and characterization of particular matters and their sources will aid the policy makers and the concerned authority to adapt measures and policies according to the circumstances. Additionally, similar intensive studies will give insight about future implications of air quality management.