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CNTs nanostructuring effect on the properties of graphite composite bipolar plate

机译:碳纳米管纳米结构对石墨复合双极板性能的影响

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摘要

Intent of present investigation is to improve the properties of graphite-polymer composite bipolar plate by nanostructuring. This involves the incorporation of different vol.% of multiwall carbon nanotubes (MWNTs) in graphite-polymer composite bipolar plate. It has been found that by inclusion of 1 vol.% of MWNTs in graphite composite plate, the electrical and thermal conductivity of nanocomposite increased by 100%. The thermal conductivity of nanocomposite plate increases from 1 W/m K to 13 W/m K in through-plane and in-plane from 25 W/m K to 50 W/m K at 1 vol.% of MWNTs. This significant enhancement is due to the orientation of MWNTs in all the directions of composite, positive synergistic effect of MWNTs and heat transfer along the axis directions. However, bending strength of nanocomposite increases by 25% and maximum augmentation is in case of 1 vol.% of MWNTs. The improvement in conductivity of nanocomposite plate is due to an increase in the electron transfer ability within the composite plate which influences the I-V performance of ultimate fuel cell. These observations confirm that the optimal content of MWNTs is 1 vol.%, in graphite-polymer composite.
机译:本研究的目的是通过纳米结构改善石墨-聚合物复合双极板的性能。这涉及在石墨-聚合物复合双极板中掺入不同体积%的多壁碳纳米管(MWNT)。已经发现,通过在石墨复合板中包含1体积%的MWNT,纳米复合材料的电导率和导热率提高了100%。纳米复合板的热导率在MWNTs的1%(体积)下,在贯穿平面内从1 W / m K增加到13 W / m K,在平面内从25 W / m K增加到50 W / mK。该显着增强是由于MWNT在复合材料的所有方向上的取向,MWNT的正协同作用以及沿轴方向的热传递。但是,纳米复合材料的弯曲强度提高了25%,在MWNTs的体积百分比为1的情况下,最大增强量增加。纳米复合板的电导率的提高归因于复合板内电子传递能力的提高,这影响了最终燃料电池的I-V性能。这些观察结果证实,在石墨-聚合物复合物中,MWNT的最佳含量为1体积%。

著录项

  • 来源
    《International journal of hydrogen energy》 |2010年第9期|4195-4200|共6页
  • 作者单位

    Carbon Technology Unit, Engineering Materials Division, National Physical Laboratory, CSIR, Dr. K. S. Krishnan Marg New Delhi 110 012 India;

    rnCarbon Technology Unit, Engineering Materials Division, National Physical Laboratory, CSIR, Dr. K. S. Krishnan Marg New Delhi 110 012 India;

    rnCarbon Technology Unit, Engineering Materials Division, National Physical Laboratory, CSIR, Dr. K. S. Krishnan Marg New Delhi 110 012 India;

    rnCarbon Technology Unit, Engineering Materials Division, National Physical Laboratory, CSIR, Dr. K. S. Krishnan Marg New Delhi 110 012 India;

    rnCarbon Technology Unit, Engineering Materials Division, National Physical Laboratory, CSIR, Dr. K. S. Krishnan Marg New Delhi 110 012 India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    bipolar plate; nanocomposite; electrical conductivity; thermal conductivity;

    机译:双极板纳米复合材料电导率导热系数;

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