Preparation and characterization of Ce_(0.8)M_(0.2)O_(2-δ) (M = Y, Gd,Sm, Nd, La) solid electrolyte materials for solid oxide fuel cells

摘要

Characteristics, such as lattice parameter, theoretical densities, thermal expansion, mechanical properties, microstructure, and ionic conductivities, of Ce_(0.8)M_(0.2)O_(2-δ) (M = Y, Gd, Sm, Nd, La) ceramics prepared by coprecipitation were systematically investigated in this paper. The results revealed that the lattice parameter and density based on the oxygen vacancy radius generally agreed with experimental results. Ce_(0.8)Sm_(0.2)O_(2-δ) ceramic sintered at 1500 ℃ for 5h possessed the maximum ionic conductivity, σ_(800) c = 6.54 × 10~2 S cm~1 with minimum activation energy, E_a = 0.7443 eV, among Ce_(0.8)M_(0.2)O_(2-δ) (M Y, Gd, Sm, Nd, La) ceramics. The thermal expansion coefficients of Ce_(0.8)M_(0.2)O_(2-δ) (M Y, Gd, Sm, Nd, La) were in the range of 15.176-15.571 ppm/ ℃, which indicates that the rare-earth oxide dopants have insignificant influence on the thermal expansion property. Trivalent, rare-earth oxide doped ceria ceramics revealed high fracture toughness, with the fracture toughness in the range of 6.393-7.003 Mpa m~(1/2). According to SEM observation, the cracks are limited to one grain diameter; therefore, the high fracture toughness of rare-earth oxide doped ceria may be due to the toughness mechanism of crack deflection at the grain boundary. Based on the results of grain size and mechanical properties, one may conclude that there is no significant dependence of fracture toughness and microhardness for Ce_(0.8)M_(0.2)O_(2-δ) ceramics on grain size. Correlation between the grain size of Ce_(0.8)M_(0.2)O_(2-δ) ceramics and the dopant species can be explained on the basis of the concept of the rate of grain growth being proportional to the boundary mobility M_b. This leads to a conclusion that the diffusion coefficient of La in Ce_(0.8)La_(0.2)O_(2-δ)>Nd in Ce_(0.8)Nd_(0.2)O_(2-δ)>Sm in Ce_(0.8)Sm_(0.2)O_(2-δ)> Gd in Ce_(0.8)Gd_(0.2)O_(2-δ)>Y in Ce_(0.8)Y_(0.2)O_(2-δ).