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Quaternary ammonia polysulfone-PTFE composite alkaline anion exchange membrane for fuel cells application

机译:季铵聚砜-PTFE复合碱性阴离子交换膜在燃料电池中的应用

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摘要

The quaternary ammonia polysulfone (QAPS) alkaline anion exchange membrane (AAEM) was previously prepared successfully. The QAPS membrane showed good ionic conductivity but poor mechanical strength and high swelling ratio. This study focused on membrane mechanical strength and dimensional stability by PTFE membrane enhancement, which increases the mechanical strength by five times and decreases the swelling ratio by 50%. The fuel cell with the resulted thinner QAPS/PTFE composite membrane with catalyst coated membrane (CCM) as the electrode showed a high power output, and the peak power density of 315 mW cm~(-2) was achieved at 50℃.
机译:先前已成功制备了季铵聚砜(QAPS)碱性阴离子交换膜(AAEM)。 QAPS膜显示出良好的离子电导率,但机械强度差且溶胀率高。这项研究的重点是通过PTFE膜增强来提高膜的机械强度和尺寸稳定性,从而使机械强度提高五倍,溶胀率降低50%。以较薄的QAPS / PTFE复合膜为电极,并以催化剂涂覆膜(CCM)为电极的燃料电池显示出高功率输出,在50℃时峰值功率密度为315 mW cm〜(-2)。

著录项

  • 来源
    《International journal of hydrogen energy》 |2013年第4期|1983-1987|共5页
  • 作者单位

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China,Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR China;

    College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan Uniuersity, Wuhan 430072, PR China;

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China;

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China,College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan Uniuersity, Wuhan 430072, PR China;

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China,Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR China;

    College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan Uniuersity, Wuhan 430072, PR China;

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China;

    Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    quaternary ammonia polysulfone; composite alkaline anion exchange; membrane; mechanical strength; dimensional stability;

    机译:季氨聚砜复合碱阴离子交换膜力学性能尺寸稳定性;

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