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Mesoporous hollow Mn-Cu-Al layered triple hydroxides nanocomposite synthesized via microwave assisted technique for symmetrical supercapacitor

机译:微波辅助技术合成介孔空心Mn-Cu-Al层状三元氢氧化物纳米复合材料

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Hollow Mn-Cu-Al layered triple hydroxides nanocomposite synthesized using microwave assisted technique possess an immense potential as a high performance electrode material for forthcoming generation energy storage warehouse. The layered triple hydroxide nanocomposite structure possesses a furry morphology with mesoporous nature. The electrochemical performance evinces the idiosyncratic architecture with highly mesoporous nature plays a prominent character in achieving high capacitance with superior life cycle stability. This structure not only supports for adequate reaction sites and also speed up electrolyte ions to reach the reacting sites. The Mn-Cu-Al layered triple hydroxide retains 93.46% of initial capacitance after 5000 cycles and having an equivalent series resistance of 0.701 Omega. Prominently, the assembled symmetric solid state supercapacitor device using Mn-Cu-Al layered triple hydroxide delivers a high energy density (101.75 W h kg(-1)) at a power density of (900 W kg(-1)). The results show the symmetric supercapacitor made from Mn-Cu-Al layered triple hydroxide nanocomposite to be a propitious candidate for energy storage applications. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:利用微波辅助技术合成的空心Mn-Cu-Al层状三元氢氧化物纳米复合材料具有巨大的潜力,可作为即将到来的发电储能库的高性能电极材料。层状三氢氧化物纳米复合结构具有毛孔形态,具有中孔性质。电化学性能证明具有高介孔性质的异质结构在获得具有优异生命周期稳定性的高电容方面具有突出的特征。这种结构不仅支持适当的反应位点,而且还可以加速电解质离子到达反应位点。 Mn-Cu-Al层状三元氢氧化物在5000次循环后保留了93.46%的初始电容,等效串联电阻为0.701Ω。突出地,使用Mn-Cu-Al层状三重氢氧化物的组装对称固态超级电容器装置以(900 W kg(-1))的功率密度提供了高能量密度(101.75 W h kg(-1))。结果表明,由Mn-Cu-Al层状三羟基氢氧化物纳米复合材料制成的对称超级电容器是储能应用的有利候选者。 (C)2017氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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