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Soldering a gas diffusion layer to a stainless steel bipolar plate using metallic tin

机译:使用金属锡将气体扩散层焊接到不锈钢双极板上

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A novel investigation to decrease the interfacial contact resistance of stainless steel bipolar plates was performed. A thin layer of Sn was electrodeposited onto a bipolar plate and subsequently joined with a gas diffusion layer through hot-pressing at a temperature around the melting point of tin. This procedure was optimised, depositing 30 mu m of Sn onto the stainless steel bipolar plate before hot-pressing at 230 degrees C and 0.5 bar for 20 min. A contact resistance of 5.45 m Omega cm(2) at 140 N cm(-2) was obtained, with low values maintained after exposure to both in-situ and ex-situ conditions. The in-situ testing in a fuel cell produced excellent results, with minor increases in contact resistance from 8.8 to 9.2 m Mu cm(2) and decreases in cell voltage from 0.714 to 0.667 V after 200 h of operation. These values are comparable to gold plated stainless steel, showing that combining a gas diffusion layer with electrodeposited Sn through hot-pressing is a promising low-cost coating for bipolar plates in PEM fuel cells. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:进行了减少不锈钢双极板界面接触电阻的新颖研究。将锡的薄层电沉积到双极板上,然后通过在锡的熔点附近的温度下进行热压而将其与气体扩散层接合。该程序经过优化,在不锈钢双极板上沉积30微米的锡,然后在230摄氏度和0.5巴下热压20分钟。在140 N cm(-2)处获得5.45 m Omega cm(2)的接触电阻,暴露于原位和异位条件后均保持较低的电阻值。在燃料电池中进行的原位测试产生了出色的结果,在运行200小时后,接触电阻从8.8微小增加到9.2 m Mu cm(2),电池电压从0.714下降到0.667V。这些值可与镀金不锈钢媲美,表明通过热压将气体扩散层与电沉积Sn结合在一起是一种有前途的低成本PEM燃料电池双极板涂层。 (C)2018氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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