Hydrogenation and dehydrogenation cycle properties of Ti-Mn based alloy Ti_(0.93)Zr_(0.07)Mn_(1.15)Cr_(0.35) in hydrogen gas

摘要

Hydrogenation and dehydrogenation cycle tests at 0 degrees C for Ti(0.93)Zr(0.07)Mn(1.15)Cr(0.3)5 were carried out 2000 cycles and more in the hydrogen gas with purity of 99.99% and 99.99999%. The capacity maintenance rates at the 2000th cycle for the first cycle were 82% and 97% for each purity hydrogen gas, respectively. It was found that the cycle durability of this alloy depends on the gas purity. By the X-ray diffraction and light element analysis, it was confirmed that the C14 type crystal structure of this alloy was maintained but the nitrogen concentration in the sample with large capacity reduction was increased after the cycle test. The main factor of the decrease in capacity of this alloy is degradation due to reaction with impurity gas components such as nitrogen. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.