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Design and experimental validation of an HT-PEFC stack with metallic BPP

机译:具有金属BPP的HT-PEFC烟囱的设计和实验验证

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This paper provides detailed insight into the design, construction, production and verification of a metallic bipolar plate for High Temperature Polymer Electrolyte Fuel Cell stacks. With a focusing on applications with power demands of 5-10 kW, the active cell area is set to a maximum of 100 cm(2). The double-plate-concept allows for liquid cooling in the inner bipolar plate compartment. Due to the bipolar plate production by hydroforming of thin stainless steel foils the structure of the coolant compartment is dependent on the gas flow field design. To ensure proper cooling functionality a co-design is necessary. The flow field design, in conjunction with the flow configuration of the reactants (reformate, air) and coolant, considers the effects of hydrogen and oxygen depletion on current density distribution, as well as the temperature profile on carbon monoxide poisoning. These specifications are based on previously published results. For validation, a 5-cell stack with commercial Membrane Electrode Assemblies was operated at 160 degrees C and 0.2 A/cm(2) and regularly interrupted for the polarization curve measurement. After 4700 h of continuous operation, the test was terminated due to a rapid voltage drop in one of the cells. In this paper, it is shown that novel metallic bipolar plates from thin metal sheets can be used for the long-term operation of High Temperature Polymer Electrolyte Fuel Cell stacks.(C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:本文提供了对用于高温聚合物电解质燃料电池堆的金属双极板的设计,构造,生产和验证的详细见解。针对功率需求为5-10 kW的应用,活动单元的面积最大设置为100 cm(2)。双板概念允许在内部双极板隔室中进行液体冷却。由于通过薄不锈钢箔的液压成型来生产双极板,冷却液室的结构取决于气流场的设计。为了确保适当的冷却功能,必须进行共同设计。流场设计与反应物(重整油,空气)和冷却剂的流动配置相结合,考虑了氢和氧消耗对电流密度分布的影响以及温度分布对一氧化碳中毒的影响。这些规范基于先前发布的结果。为了验证,带有商业膜电极组件的5电池堆栈在160摄氏度和0.2 A / cm(2)下运行,并定期中断以进行极化曲线测量。连续运行4700小时后,由于其中一个电池的电压快速下降,测试终止。本文显示,由薄金属板制成的新型金属双极板可用于高温聚合物电解质燃料电池堆的长期运行。(C)2018 Hydrogen Energy Publications LLC。由Elsevier Ltd.出版。保留所有权利。

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