首页> 外文期刊>International journal of hydrogen energy >Electrochemical performance of nanostructured LNF infiltrated onto LNO cathode for BaZr_(0.1)Ce_(0.7)Y_(0.2)O_(3-δ)-based solid oxide fuel cell
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Electrochemical performance of nanostructured LNF infiltrated onto LNO cathode for BaZr_(0.1)Ce_(0.7)Y_(0.2)O_(3-δ)-based solid oxide fuel cell

机译:BaZr_(0.1)Ce_(0.7)Y_(0.2)O_(3-δ)基固体氧化物燃料电池渗透到LNO阴极的纳米结构LNF的电化学性能

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摘要

In this paper, the electrochemical performance of nanostructured LaNi0.6Fe0.4O3-delta (LNF) infiltrated La2NiO4+delta (LNO) material was evaluated as a potential cathode for BaZr0.1Ce0.7Y0.2O3-delta (BZCY)-based proton-conducting solid oxide fuel cell (H-SOFC). The performance of LNO backbone cathodes with different loading amounts of LNF infiltrated phase were investigated, and electrochemical studies implied that the single cell with about 31 wt % LNF infiltrated cathode exhibited the lowest polarization resistance of 0.027 Omega cm(2) and the highest maximum power density of 969 mWcm(-2) at 700 degrees C, which were encouraging compared with that in previous reports of cobalt-free cathodes for H-SOFCs. This work demonstrated that the infiltrated LNF-LNO cathode had a great potential for H-SOFC and the optimization of the loading amount of LNF nanoparticles on LNO was critical for the fuel cell performance. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:本文以渗入的La2NiO4 +δ(LNO)纳米结构LaNi0.6Fe0.4O3-δ(LNF)材料的电化学性能作为BaZr0.1Ce0.7Y0.2O3-δ(BZCY)基质子的潜在阴极进行了评估。导电固体氧化物燃料电池(H-SOFC)。研究了LNF渗透相的不同负载量下LNO骨架阴极的性能,电化学研究表明具有约31 wt%LNF渗透阴极的单电池表现出最低的极化电阻0.027 Omega cm(2)和最高的最大功率密度在700摄氏度时为969 mWcm(-2),与以前的H-SOFCs无钴阴极报告相比,这令人鼓舞。这项工作表明,渗透的LNF-LNO阴极具有很大的H-SOFC潜力,LNO上LNF纳米粒子的负载量的优化对于燃料电池的性能至关重要。 (C)2018氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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