Enhancing Coercivity of Sintered Nd-Fe–B Magnets by Nanoparticle Addition

摘要

In this paper, we investigated the influence of addition of ${rm Dy}_{{40}}{rm Nd}_{40}{rm Al}_{{30}}$ nanoparticles on the structure and magnetic properties of sintered Nd-Fe–B magnets. The nanoparticles with a size smaller than 50 nm were prepared using high-energy ball milling method and then mixed with micrometer ${rm Nd}_{{2}}{rm Fe}_{{14}}{rm B}$ powder before magnetic anisotropic pressing, vacuum sintering, and annealing. The structure of the magnets was thoroughly analyzed using X-ray diffraction and electron microscopy techniques. The magnetic properties of the magnets were investigated on a pulsed field magnetometer. The atoms of Dy were detected mainly at the grain boundaries and partly in the near-boundary area of the grains. On adding 2% of the nanoparticles, the coercivity of the magnets is enhanced by quite a large amount, from 12 kOe for the unadded magnets to 21 kOe for the added ones. The large increase of the coercivity is probably due to the diffusion of Dy to the ${rm Nd}_{{2}}{rm Fe}_{{14}}{rm B}$ grains to form $({rm Nd,Dy})_{{2}}{rm Fe}_{{14}}{rm B}$ phases with high magnetocrystalline anisotropy. The nanoparticles might make Dy distribute more homogeneously and diffuse to the ${rm Nd}_{{2}}{rm Fe}_{{14}}{rm B}$ grains more efficiently.