Experimental and Simulation Analysis of the Evolution of Residual Stress Due to Expansion via CMAS Infiltration in Thermal Barrier Coatings

摘要

The failure behavior of thermal barrier coatings (TBCs) involves multilayered systems infiltrated with calcium–magnesium–alumino-silicates (CMAS). The metastable tetragonal phase is mainly composed of 7YSZ (7 mol.% Y2O3-stabilized ZrO2), and it destabilizes into the Y-lean tetragonal phase, which may be induced by CMAS infiltration, and transforms into a monoclinic phase during cooling. The phase transformation leads to volume expansion around the CMAS-rich layer. Furthermore, it is shown that the spalling of the coating system emerges when the surface of the coating system is subjected to significant residual stress. In this study, a double-cantilever beam model is established to describe the macroscopic phenomenon of thermal buckling induced via CMAS. The result of the buckle height is used to demonstrate the consistency of the experiment and finite element simulation. The experimental parameters are imported into a multilayer cantilever beam model to analyze the interfacial stresses due to CMAS infiltration. The finite element results indicate that the phase transformation leads to damage in the coating system wherein the interfacial stresses due to phase transformation are 27% higher than those in the model without phase transformation.