Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy

Seongchul Park; Juhyang Shin; Hojeong Yoon; Manho Lim

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Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy

机译：由飞秒红外光谱法探测CCL4溶液中CF2I2的Photodissociation Dynamics

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Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.

机译：350nm激发溶液中CF2i2在溶液中的光积极的动态。立即解离一个I原子，所有解离的I脱位纠正形成反应物或异构体，以迅速释放产生CF2的I2分子，其双分半反应以产生C2F4。

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《Bulletin of the Korean Chemical Society》 |2020年第10期|共3页
作者
Seongchul Park; Juhyang Shin; Hojeong Yoon; Manho Lim;
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中图分类化学;
关键词
Reaction in solutionGeminate rebindingTimeresolved infrared spectroscopySolvent cageSolventassisted reactionisoHalomethane;

机译：溶解液中的反应regIndingtimeresolved红外光谱肌肉葡萄宫内甲烷;

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1. Photodissociation Dynamics of CF2I2 in CC14 Solution Probed by Femtosecond Infrared Spectroscopy [J] . Seongchul Park, Juhyang Shin, Hojeong Yoon Bulletin of the Korean Chemical Society . 2020,第10期

机译：由飞秒红外光谱法探测CC14溶液中CF2I2的光积极性动态
2. Conformer-Specific Photodissociation Dynamics of CF2ICF2I in Solution Probed by Time-Resolved Infrared Spectroscopy [J] . Park Seongchul, Lee Taegon, Shin Juhyang, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2020,第39期

机译：溶液中CF2ICF2i的特异性光度光度分辨红外光谱法探测的特异性光学质动力学
3. Complete photodissociation dynamics of CF2I2 in solution [J] . Park Seongchul, Shin Juhyang, Yoon Hojeong, Physical chemistry chemical physics: PCCP . 2019,第13期

机译：溶液中CF2I2的完整光度分离动态
4. Photodissociation Dynamics of Acetone in the Gas Phase and in Solution Studied by Transient Absorption and Femtosecond Stimulated Raman Spectroscopy [C] . Seung Min En, Hye Ran Koh, Ilseung Yang, International Conference on Raman Spectroscopy . 2010

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5. Molecular Dynamics of O(1D) + CCl4 → ClO + CCl3 Probed by Cavity Enhanced Sub-Thz Spectroscopy [D] . O'Neal, Ryan. 2020

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6. Ligand dynamics in the photodissociation of carboxyhemoglobin by subpicosecond transient infrared spectroscopy. [O] . L Rothberg, T M Jedju, R H Austin 1990

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Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy

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