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Synthesis and Evaluation of a Water-Swelling Polymer Plugging Agent SWL-1

机译:水溶性聚合物堵塞剂SWL-1的合成与评价

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In this paper, to solve the problems of low water absorption and weak pressure bearing capacity of current plugging materials, acrylic acid (AA), acrylamide (AM), and sodium allyl sulfonate (SAS) are used as monomers, and soluble starch is used as grafting. Material, the use of free radical aqueous solution method to synthesize the plugging agent SWL-1 with good water absorption and strong salt resistance. The monomer ratio is set as n (AA):n (AM):n (SAS) = 5:2:1, the experimental synthesis temperature is 70°C, and the orthogonal experiment is used to determine the experimental synthesis conditions as AA neutralization degree 80%, The amount of initiator is 0.60%, the amount of crosslinking agent is 0.50%, the ratio of monomer to starch is 7:1, and the amount of calcium carbonate is 13%. The comprehensive evaluation of the performance of the plugging agent SWL-1 shows that the water absorption performance at 60°C is the best 268.78 g/g, and the water absorption performance in 8% NaCl, 0.9% CaCl_(2) and composite brine is 21.5 g/g, 12.5 g/g and 24.9 g/g, indicating good resistance to sodium and calcium, the water retention rate is still higher than 30% after 15 days at 160°C. The sand bed plugging test found that the maximum pressure of SWL-1 was 7 MPa, and the crack plugging test found that when the crack width was 1 mm, 2 mm, and 3 mm, the maximum compressive strength of SWL-1 was 10 MPa. The acid solubility test showed that the maximum pressure was 10 MPa. The highest rate is 86.38%.
机译:在本文中,为了解决电流堵塞材料的低吸水性和弱压承载能力,用作单体,使用丙烯酸(AA),丙烯酰胺(AA),丙烯酰胺(AA)和烯丙基磺酸钠(SAS)作为单体,使用可溶性淀粉嫁接。材料,使用自由基水溶液方法合成堵塞剂SW1-1,具有良好的吸水性和强的耐盐性。单体比设定为n(aa):n(am):n(sas)= 5:2:1,实验合成温度为70℃,正交实验用于确定实验合成条件作为AA中和度80%,引发剂的量为0.60%,交联剂的量为0.50%,单体与淀粉的比例为7:1,碳酸钙的量为13%。综合评价堵塞剂SWL-1的性能表明,60℃的吸水性性能是最佳的268.78g / g,以及8%NaCl,0.9%CaCl_(2)和复合盐水中的吸水性能21.5g / g,12.5g / g和24.9g / g表示良好的耐钠和钙,水保留率在160℃下在15天后仍高于30%。砂床堵塞试验发现SWL-1的最大压力为7MPa,并且裂缝堵塞试验发现,当裂缝宽度为1mm,2mm和3毫米时,SWL-1的最大抗压强度为10 MPA。酸溶解度试验显示最大压力为10MPa。最高率为86.38%。

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