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首页> 外文期刊>Macedonian Journal of Chemistry and Chemical Engineering >Preparation and recycling of polymer eco-composites I. comparison of the conventional molding techniques for preparation of polymer eco-composites
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Preparation and recycling of polymer eco-composites I. comparison of the conventional molding techniques for preparation of polymer eco-composites

机译:聚合物生态复合材料的制备及再循环I.常规模塑技术的比较制备聚合物生态复合材料

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摘要

The interest in natural fiber-reinforced polymer composites is growing rapidly due to their high performance in terms of mechanical properties, significant processing advantages, excellent chemical resistance, low cost and low density. In this study, the compression and injection molding of polypropylene (PP) and polylactic acid (PLA) based composites reinforced with rice hulls or kenaf fibers was carried out and their basic properties were examined. Rice hulls from rice processing plants and natural lignocellulosic kenaf fibers from the bast of the plant Hibiscus Cannabinus represent renewable sources that could be utilized for composites. Maleic anhydride grafted PP (MAPP) and maleic anhydride grafted PLA (MAPLA) were used as coupling agents (CA) to improve the compatibility and adhesion between the fibers and the matrix. Composites containing 30 wt % reinforcement were manufactured by compression and injection molding, and their mechanical and thermal properties were compared. It was found that the techniques applied for manufacturing of the eco-composites under certain processing conditions did not induce significant changes of the mechanical properties. The flexural strength of the compressed composite sample based on PP and kenaf is 51. 3 MPa in comparison with 46.7 MPa for the same composite produced by injection molding technique. Particularly, PP-based composites were less sensitive to processing cycles than PLA-based composites. The experimental results suggest that the compression and injection molding are promising techniques for processing of eco-composites. Moreover, the PP-based composites and PLA-based composites can be processed by compression and injection molding. Both composites are suitable for applications as construction materials.
机译:天然纤维增强聚合物复合材料的兴趣由于其在机械性能方面的高性能,显着的加工优势,优异的耐化学性,低成本和低密度而高,因此迅速增长。在该研究中,进行了用稻壳或keanaF纤维增强的聚丙烯(PP)和聚乳酸(PLA)复合材料的压缩和注射成型,并检查其基本性质。来自水稻加工厂和天然木质纤维素kEnaf纤维的稻壳来自植物芙蓉大麻的植物,代表可再生来源,可用于复合材料。马来酸酐接枝的PP(MAPP)和马来酸酐接枝PLA(MAPLA)用作偶联剂(CA)以改善纤维与基质之间的相容性和粘附性。通过压缩和注塑制造含有30wt%增强材料的复合材料,并比较其机械和热性能。结果发现,在某些加工条件下施加用于制造生态复合材料的技术并未诱导机械性能的显着变化。基于PP和KENAF的压缩复合样品的弯曲强度为51.3MPa,相对于通过注塑技术产生的相同复合材料的46.7MPa相比。特别地,基于PP的复合材料对加工循环的敏感性小于PLA基复合材料。实验结果表明,压缩和注塑是用于加工生态复合材料的有前途的技术。此外,可以通过压缩和注塑来处理基于PP的复合材料和基于PLA的复合材料。两种复合材料适用于应用作为建筑材料。

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