The structure of the title hydrated mol-ecular salt, C 10 H 8 NS ·Cl ? ·H 2 O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH 2 Cl 2 and an aqueous solution of [Bu 4 N]Cl, contains π -stacked cations [plane-to-plane separation = 3.338?(4)–3.356?(4)??] and features chains built by alternating Cl ? anions and H 2 O mol-ecules connected by O—H?O hydrogen bonds. The cation shows whole-mol-ecule disorder over two flipped orientations in a 0.853?(3):0.147?(3) ratio.
展开▼
机译：标题水合摩尔胚盐的结构，C 10 H 8 NS·Cl？ ·H 2 O，通过喹啉-8-硫醇酸钠Na（Quin-8-S）与CH 2 Cl 2的反应获得，并含有π-堆积的阳离子[平面至-plane分离= 3.338？（4）-3.356？（4）??]和通过交替CL建造的链条通过O-H·O氢键连接的阴离子和H 2 O Mol-Ecules。该阳离子显示出在0.853中的两种翻转方向上的全摩尔生态病症？（3）：0.147？（3）比率。
展开▼
