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Hydrogen Permeation Behavior of Scratch on Zn Coated Steel during 1000 Hours Wet and Dry Corrosion Test

机译:1000小时湿腐蚀试验期间Zn涂层钢刮擦的氢渗透行为

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In this study, hydrogen permeation current from scratch formed on Zn coated steel during 1000 h wet and dry cyclic corrosion test was investigated. The scratch was fabricated by focused pulsed Nd: YAG laser irradiation. The obtained hydrogen permeation current has peaks during wetting, and the peak currents decrease with time. Formation of Zn corrosion products prevent hydrogen entry. After the test, there are Zn oxide (ZnO) on the substrate steel, hydrozincite (Zn_(5)(OH)_(6)(CO_(3))_(2)) around the scratch boundary and simonkolleite (Zn_(5)(OH)_(8)Cl_(2)) on Zn coated region. It is suggested that pH change with distance from the formed scratch is the reason for the composition of Zn corrosion products change with location.
机译:在该研究中,研究了在1000h湿循环试验期间在Zn涂层钢上形成的刮擦的氢渗透电流。通过聚焦脉冲Nd:YAG激光照射来制造划痕。所得氢渗透电流在润湿期间具有峰,峰值电流随时间减少。 Zn腐蚀产品的形成防止氢气进入。试验后,围绕划痕边界和Simonkolleite(Zn_(5)围绕施用衬底钢(Zn_(5)(OH)_(2))(CO_(3))_(2))上存在Zn氧化物(ZnO)(Zn_(5)(OH)(2))(Zn_(5 Zn涂层区域的(OH)_(8)CL_(2))。建议距离成立划痕的距离的pH变化是Zn腐蚀产品组成的原因随着位置的变化。

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