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首页> 外文期刊>Atmospheric Measurement Techniques Discussions >Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
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Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station

机译:在Karlsruhe TCCON站测量的近红外太阳能FTIR光谱改进了对近红外太阳能FTIR光谱的燃气丰富的检索

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We present a?modified retrieval strategy for solar absorption spectra recorded by the Karlsruhe Fourier Transform Infrared (FTIR) spectrometer, which is operational within the Total Carbon Column Observing Network (TCCON). In typical TCCON stations, the 380011?000 cm1 spectral region is measured on a?single extended Indium Gallium Arsenide (InGaAs) detector. The Karlsruhe setup instead splits the spectrum across an Indium Antimonide (InSb) and InGaAs detector through the use of a?dichroic beam splitter. This permits measurements further into the mid-infrared?(MIR) that are of scientific interest, but are not considered TCCON measurements. This optical setup induces, however, larger variations in the continuum level of the solar spectra than the typical TCCON setup. Here we investigate the appropriate treatment of continuum-level variations in the retrieval strategy using the spectra recorded in Karlsruhe. The broad spectral windows used by TCCON require special attention with respect to residual curvature in the spectral fits. To accommodate the unique setup of Karlsruhe, higher-order discrete Legendre polynomial basis functions have been enabled in the TCCON retrieval code to fit the continuum. This improves spectral fits and air-mass dependencies for affected spectral windows. After fitting the continuum curvature, the Karlsruhe greenhouse gas records are in good agreement with other European TCCON data sets.
机译:我们展示了由Karlsruhe傅里叶变换红外(FTIR)光谱仪记录的太阳能吸收光谱的修改检索策略,其在总碳柱观察网络(TCCON)内是可操作的。在典型的TCCON站中,380011?000 cm1光谱区域以α单延长铟镓砷(Ingaas)检测器测量。 Karlsruhe设置通过使用A二向分子分离器来将铟锑苷(INSB)和IngaAs检测器分裂。这允许进一步进入中红外线的测量?(MIR),这些兴趣是科学兴趣的,但不考虑TCCON测量。然而,该光学设置引起了太阳光谱的连续级别比典型的TCCON设置更大的变化。在这里,我们调查使用Karlsruhe中记录的光谱来调查对检索策略中的连续级别变化的适当处理。 TCCON使用的广谱窗口在光谱配合中的剩余曲率方面需要特别注意。为了适应Karlsruhe的独特设置,在TCCON检索代码中已经启用了高阶离散的传奇多项式基础函数以适应连续体。这提高了受影响的光谱窗口的光谱拟合和空气质量依赖性。在拟合连续曲率后,卡尔斯鲁赫温室气体记录与其他欧洲TCCON数据集良好。

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