To evaluate the effect of temporary emission control measures on air quality during the 2016 G20 summit held in Hangzhou, China, an intensive field campaign was conducted with a focus on aerosol chemistry and gaseous precursors from 15?August to 12?September?2016. The concentrations of fine particles were reduced during the intense emission control stages, with the reduction of carbonaceous matter being mostly responsible for this observed decrease. This, in turn, was mainly ascribed to the decrease of secondary organic aerosols via the suppression of daytime peak secondary organic carbon (SOC)formation. Although the regional joint control was enacted extending to the Yangtze River Delta region, the effect of long-range transport on the air quality of Hangzhou was ubiquitous. Unexpectedly high NOx concentrations were observed during the control stage, when the strictest restriction on vehicles was implemented, owing to contributions from upstream populous regions such as Jiangsu and Shandong provinces. In addition, the continental outflow traveling over the ocean triggered a short pollution episode on the first day of the G20 summit, resulting in a significant enhancement of the nitrogen/sulfur oxidation rates. In the wake of the summit, all air pollutants evidently rebounded after the various control measures were lifted. Overall, the fraction of secondary inorganic aerosols (SIA; in this case sulfate, nitrate, and ammonium aerosols – SNA) in PM2.5 increased as relative humidity increased; however, the overall concentration of PM2.5 did not increase. Aerosol components that had distinctly different sources and formation mechanisms, e.g., sulfate/nitrate and elemental carbon, exclusively showed strong correlations during the regional/long-range transport episodes. The sulfate, nitrate, and ammonium to elemental carbon (SNA∕EC) ratio, which was used as a proxy for assessing the extent of secondary inorganic aerosol formation, was found to be significantly enhanced under transport conditions from northern China. This study highlighted that emission control strategies were beneficial for curbing particulate pollution, in addition to the fact that regional/long-range transport may offset local emission control effects to some extent.
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