Bis(1-phenyl-imidazole)[5,10,15,20-tetrakis(2-pival-amidophenyl)porphinato]iron(III) tri-fluoro-methane-sulfonate chloro-benzene disolvate

摘要

The title complex, [Fe(C 64 H 64 N 8 O 4 )(C 9 H 8 N 2 ) 2 ](CF 3 O 3 S)·2C 6 H 5 Cl, has an unusual relative orientation of the two planar axial ligands [dihedral angle between the two imidazole planes = 46.55?(9)°]. The average equatorial Fe—N bond length is 1.974?(3)??; the axial distances are 1.9628?(19) and 1.9932?(19)??. The porphyrin core displays modest ruffling. Disorder is modeled for three of the tert -butyl groups of the pickets. In the crystal, a modest π – π inter-action exists between adjacent phenyl rings related by an inversion center, and hydrogen bonds connect the tri-fluoro-methane-sulfonate oxygen atoms to the amide groups of the picket substituents.