Effect of Emulsifier on the Structure and Properties of Waterborne Silicone Antifouling Coating

摘要

Three-component waterborne silicone antifouling coatings, which could cured at room temperature, were prepared, respectively, with cationic (stearyl trimethyl ammonium bromide) or anionic (sodium dodecyl benzene sulfonate) silicone emulsion as a film-forming substance, γ-methacryloxypropyltrimethoxysilane as a curing agent and dibutyltin dilaurate as a catalyst. The effect of emulsifier on the structure and properties of silicone coating was studied. The results showed that the coating with cationic silicone emulsion had high crosslinking density, and its surface is smooth. The surface of the coating prepared by the anionic silicone emulsion is rough. Emulsifier type had no obvious effect on the surface free energy of the waterborne silicone coating. The coatings have the characteristics of low surface energy and excellent bacterial desorption properties. Stearyl trimethyl ammonium bromide in the cured coating can reduce the adhesion of marine bacteria on the coating surface. Both the emulsifiers can inhibit the activity of Navicula Tenera. The waterborne silicone coating prepared by cationic silicone emulsion has better comprehensive mechanical properties and antifouling performance.