Efficient Degradation of Refractory Organics Using Sulfate Radicals Generated Directly from WO 3 Photoelectrode and the Catalytic Reaction of Sulfate

摘要

An environment-friendly method of efficiently degrading refractory organics using SO 4 ?￠???? ?￠???￠ generated directly from a WO 3 photoelectrode and a catalytic reaction of sulfate was proposed, in which the cycling process of SO 4 2?￠???? ?￠???? SO 4 ?￠???? ?￠???￠ ?￠???? SO 4 2?￠???? was achieved in the treatment of organic pollutants without any other activator and without the continuous addition of sulfate. The results show that the removal efficiency for a typical refractory organics of methyl orange (MO) with 5 mg/L was up to 95% within 80 min, and merely 3% by photolysis and 19% by photocatalysis, respectively, under similar conditions. The rate constant for the disposal of MO at pH 2, in which SO 4 ?￠???? ?￠???￠ instead of HO?￠???￠ is the main oxidizer confirmed by radical scavenger experiment, is up to 5.21 ???? 10 ?￠????4 s ?￠????1 , which was ~6.6 times that (7.89 ???? 10 ?￠????5 s ?￠????1 ) under neutral condition, in which HO?￠???￠ is the main oxidizer. The concentration of active persulfate (S 2 O 8 2?￠???? , SO 5 2?￠???? , and SO 4 ?￠???? ?￠???￠) species at pH 2 was up to 0.38 mM, which was ~16-fold as much as that (0.023 mM) in neutral conditions. The method provides a new approach for the treatment and resource utilization of sulfate wastewater.