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Synthesis and Characterization of Rare Earth Ion Doped Nano ZnO

机译:稀土离子掺杂纳米ZnO的合成与表征

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Zinc oxide (ZnO) doped with erbium at different concentrations was synthesized by solid-state reaction method and characterized by X-ray diffraction (XRD), scanning electron microscopic (SEM), UV-absorption spectroscopy, photoluminescence (PL) study and vibrating sample magnetometer. The XRD studies exhibit the presence of wurtzite crystal structure similar to the parent compound ZnO in 1% Er~(3+) doped ZnO, suggesting that doped Er~(3+) ions sit at the regular Zn~(2+) sites. However, same studies spread over the samples with Er~(3+) content>1% reveals the occurrence of secondary phase. SEM images of 1% Er~(3+) doped ZnO show the polycrystalline nature of the synthesized sample. UV-visible absorption spectrum of Er~(3+) doped ZnO nanocrystals shows a strong absorption peak at 388 nm due to ZnO band to band transition. The PL study exhibits emission in the visible region, due to excitonic as well as defect related transitions. The magnetization-field curve of Er~(3+) doped ZnO nanocrystals showed ferromagnetic property at room-temperature.
机译:通过固相反应法合成了不同浓度的do掺杂的氧化锌(ZnO),并通过X射线衍射(XRD),扫描电子显微镜(SEM),紫外吸收光谱,光致发光(PL)研究和振动样品进行了表征。磁力计。 XRD研究表明,在1%Er〜(3+)掺杂的ZnO中存在类似于母体化合物ZnO的纤锌矿晶体结构,表明掺杂的Er〜(3+)离子位于规则的Zn〜(2+)位置。然而,对Er〜(3+)含量> 1%的样品进行的相同研究也揭示了次生相的发生。 1%Er〜(3+)掺杂的ZnO的SEM图像显示了合成样品的多晶性质。 Er〜(3+)掺杂的ZnO纳米晶体的紫外可见吸收光谱在388 nm处具有很强的吸收峰,这是由于ZnO的能带跃迁。由于激子以及缺陷相关的跃迁,PL研究显示出可见光区域的发射。掺Er〜(3+)的ZnO纳米晶体的磁化场曲线在室温下表现出铁磁性。

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