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Effect of H 2 O 2 on the Separation of Mo-Bi-Containing Ore by Flotation

机译:H 2 O 2对浮选分离含钼铋矿石的影响

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Hydrogen peroxide (H 2 O 2 ) is a strong oxidizer that causes non-selective oxidation of sulfide minerals, and its influence on bismuth sulfide ores is not well-documented. In this study, H 2 O 2 was proposed as an alternative bismuthinite depressant, and its effect on a Mo-Bi-containing ore was intensively investigated by batch flotation tests. Results showed that the addition of H 2 O 2 significantly destabilized the froth phase, thus decreasing the solids and water recovery. The recovery of bismuth in molybdenum concentrate was dramatically decreased to 4.64% by H 2 O 2 compared with that in the absence of H 2 O 2 (i.e., 50.14%). The modified first-order kinetic model demonstrated that the flotation rate of molybdenite slightly declined after H 2 O 2 addition, whereas that of bismuthinite was drastically reduced from 0.30 min ?1 to 0.08 min ?1 under the same condition. Simulation revealed that H 2 O 2 affected the floatability of both molybdenite and bismuthinite but resulted in more detrimental effect to bismuthinite. Hence, H 2 O 2 has the potential to act as an effective depressant in bismuth sulfide ore flotation.
机译:过氧化氢(H 2 O 2)是一种强氧化剂,会引起硫化​​物矿物的非选择性氧化,并且对硫化铋矿石的影响尚无充分文献记载。在这项研究中,有人提议使用H 2 O 2作为替代的双菱镁矿抑制剂,并通过分批浮选试验深入研究了其对含Mo-Bi矿石的影响。结果表明,H 2 O 2的添加显着破坏了泡沫相的稳定性,从而降低了固体和水的回收率。与不存在H 2 O 2的情况(即50.14%)相比,通过H 2 O 2可使钼精矿中的铋的回收率显着下降至4.64%。修改后的一级动力学模型表明,加入H 2 O 2后,辉钼矿的浮选速率略有下降,而在相同条件下,亚菱锰矿的浮选速率从0.30 min?1大幅降低至0.08 min?1。模拟表明,H 2 O 2影响辉钼矿和双亚锡矿的漂浮性,但对双亚锡矿产生更大的不利影响。因此,H 2 O 2有潜力在硫化铋矿石浮选中作为有效的抑制剂。

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