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2,4-Di-tert-butyl-6-({[(R)-1-phenyl-eth-yl]amino}-meth-yl)phenol

机译:2,4-二叔丁基-6-({[((R)-1-苯基-乙基-基]氨基}-甲基-基)酚

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摘要

There are two mol-ecules in the asymmetric unit of the title compound, C23H33NO, in which the dihedral angles between the aromatic rings are 72.1?(3) and 89.0?(2)°. One of the mol-ecules features a tert-butyl group disordered over two sets of sites in a 0.545?(13):0.455?(13) ratio. Both mol-ecules feature an intra-molecular O—H?N hydrogen bond, which closes an S(6) ring. Neither of the N—H groups participates in hydrogen bonds, perhaps due to steric crowding.
机译:标题化合物C23H33NO的不对称单元中有两个摩尔晶胞,其中芳环之间的二面角为72.1°(3)和89.0°(2)°。其中一种分子具有叔丁基,在两个位点上以0.545?(13):0.455?(13)的比率无序排列。这两个分子都具有一个分子内OH HN氢键,该氢键封闭一个S(6)环。 NH基团都不参与氢键,可能是由于空间拥挤。

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