{6,6′-Di-methyl-2,2′-bis--[(2-oxido-benzyl--idene)amino]-1,1′-bi-phenyl-κ4O,N,N′,O′}bis--(propan-2-olato-κO)titanium(IV) n-hexane hemisolvate

摘要

The mononuclear TiIV?title complex, [Ti(C28H22N2O2)(C3H7O)2]·0.5C6H14, crystallizes as an?n-hexane hemisolvate. The TiIV?atom is coordinated by a dianionic tetra-dentate biphenyl Schiff base ligand and two O atoms of two propan-2-olate anions in a distorted TiN2O4?octa-hedral coordination geometry, in which the two N atoms are in a?cis?configuration. In the crystal, complex mol-ecules are stacked parallel to [100], leaving space for channels parallel to [001] where the solvent mol-ecules are located.