Efficient and eco-friendly synthesis of quinoxalines derivatives catalyzed by acidic ionic liquids at room temperature

摘要

In this research, we have developed cheap recyclable and task-specific acidic ionic liquids (AILs) 1-hydrogen-3-methylimidazolium hydrogen sulfate [Hmim]HSO4, 1-hydrogen-3-methylimidazolium chloride [Hmim]Cl, 2-pyrrolidonium hydrogensulfate [Hnhp]HSO4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. The products could be separated from the catalyst simply by filtration and the catalyst could be recycled and reused several times without noticeable loss of efficiency.