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Adsorption and Corrosion Inhibition Properties of Cefadroxil on Mild Steel in Hydrochloric Acid

机译:盐酸头孢氨苄在低碳钢上的吸附和缓蚀性能。

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Corrosion inhibition of mild steel in 1M HCl by cefadroxil has been studied using electrochemicalimpedance spectroscopy (EIS), potentiodynamic polarization and weight loss methods. The inhibitor-4 -1 showed more than 96% inhibition efficiency at optimum concentration of 11.010 mol l . The resultsobtained by these techniques were well supported by the atomic force microscopy. Thermodynamicparameters obtained support physical adsorption mechanism and the experimental data fits well intothe Langmuir adsorption isotherm model. Potentiodynamic polarization suggests that cefadroxil act asmixed type inhibitor. Thermodynamic parameters suggest the adsorption is spontaneous andexothermic process. The results obtained from the three methods used are in good agreement.
机译:使用电化学阻抗谱(EIS),电位动力学极化法和失重法研究了头孢氨苄在1M HCl中对低碳钢的腐蚀抑制作用。在最佳浓度11.010 mol l下,抑制剂4 -1表现出超过96%的抑制效率。这些技术获得的结果得到原子力显微镜的充分支持。获得的热力学参数支持物理吸附机理,实验数据与Langmuir吸附等温线模型吻合良好。电位动力学极化表明,头孢羟氨苄可作为混合型抑制剂。热力学参数表明吸附是自发和放热过程。从所使用的三种方法获得的结果非常吻合。

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