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Influence of characteristics of recycling agent on the early and long-term performance of regenerated SBS modified bitumen

机译:再生剂特性对再生SBS改性沥青的早期和长期性能的影响

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The increasing reclaimed asphalt pavement mixture causes environmental pollution and a waste of resource, which could be resolved by the asphalt recycling technology. In this paper, corn oil, waste engine oil, vacuum stream oil and cashew shell oil are used for rejuvenating aged SBS modified asphalt (ASMA), and the effect of composition, structure and thermal-oxidative stability of recycling agents on the early and long-term performance of rejuvenated binder are thoroughly investigated. The results indicate cashew shell oil with nut phenol derivatives has the best rejuvenating effect on ASMA, corn oil containing aliphatic hydrocarbons is more conducive to improving the low temperature performance of rejuvenated ASMA, and vacuum stream oil containing nonpolar alkane compound shows the worst regeneration effect. Meanwhile, simultaneous thermal analysis reveals nonpolar aliphatic hydrocarbons vacuum stream oil has the poorest thermal stability for its lowest initial decomposition temperature 146 degrees C, while initial decomposition temperature of cashew shell oil and corn oil are all over 200 degrees C. The changes of physical and rheological properties of cashew shell oil rejuvenated ASMA after aging are much smaller than that of others, which indicates cashew shell oil with excellent thermal-oxidative stability is more conductive to inhibiting the transition from viscosity to elasticity of rejuvenated binder in the aging process. While vacuum stream oil rejuvenated ASMA shows the most serious aging degree, suggesting the poor thermal-oxidative stability of recycling agents has adverse effects on the anti-aging properties of rejuvenated binder. Infrared spectrum analysis indicates the aging index growth rate of cashew shell oil rejuvenated ASMA is the smallest, also demonstrating the best aging resistance of cashew shell oil rejuvenated ASMA. The correlation coefficients between sulfoxide index and physical-rheological properties are almost all higher than 0.90, while that between sulfoxide index and physical-rheological properties are lower than 0.71, therefore sulfoxide index can be a better indicator for estimating the physical-rheological properties of rejuvenated SBS modified bitumen in the service. (C) 2019 Elsevier Ltd. All rights reserved.
机译:越来越多的再生沥青路面混合物造成环境污染和资源浪费,可以通过沥青回收技术解决该问题。本文使用玉米油,废机油,真空流油和腰果壳油使SBS改性沥青(ASMA)老化,并使再生剂的组成,结构和热氧化稳定性对早期和长期的影响彻底研究了再生的粘合剂的长期​​性能。结果表明,含坚果酚衍生物的腰果壳油对ASMA的再生效果最好,含脂肪烃的玉米油更有利于改善再生的ASMA的低温性能,而含非极性烷烃化合物的真空流油则再生效果最差。同时,同时进行的热分析表明,非极性脂肪族烃真空物流油的最低初始分解温度为146摄氏度,而热稳定性最差,而腰果壳油和玉米油的初始分解温度均超过200摄氏度。老化后再生的ASMA腰果壳油的流变特性远小于其他,这表明具有优异的热氧化稳定性的腰果壳油在老化过程中更有助于抑制再生的粘合剂从粘度转变为弹性。真空流油再生的ASMA表现出最严重的老化程度,这表明回收剂的热氧化稳定性差对再生的粘合剂的抗老化性能产生不利影响。红外光谱分析表明,腰果壳油再生ASMA的老化指数增长率最小,也证明了腰果壳油再生ASMA的最佳抗老化性。亚砜指数与物理流变性能之间的相关系数几乎都高于0.90,而亚砜指数与物理流变性能之间的相关系数低于0.71,因此亚砜指数可以更好地指示再生后的物理流变性能SBS在服务中改性沥青。 (C)2019 Elsevier Ltd.保留所有权利。

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