Three-dimensional simulations of ignition of composite solid propellants

摘要

This paper reports three-dimensional direct numerical simulations of ignition of a composite AP (ammonium perchlorate)-HTPB (hydroxyl-terminated polybutadiene) propellant subjected to a constant flux phi. The model includes solid heat transfer, gas-phase combustion with global kinetics and explicit description of propellant microstructure. Simulations show that ignition starts from AP particles because of primary AP/binder flame. Goo-go computations reveal an unreported intermediate regime between go and no-go with apparent quenching followed by a delayed ignition. This delay is linked to a slow flame spreading from localized scattered hot spots on surface. In accordance with experiments, ignition delays deviate from classical phi(-2) scaling for high flux and low pressure conditions. For intense flux levels, simulations attest deradiation extinction upon flux termination meaning that there is a critical flux above which ignition is no longer possible. The role of AP particle shape and size distribution on ignition delay is studied and predicted to be limited. The effect of propellant surface conditions is also investigated and can lead to substantial effects on ignition delay. Finally, semi-transparent propellants are also considered and low absorption materials result in longer ignition times, reduced phi-dependence, and absence of de radiation extinction. This work eventually highlights the importance of microstructure-based details in the physics of composite propellant ignition and opens the way towards better understanding of the role of AP particles. (C) 2016 The. Combustion Institute. Published by Elsevier Inc. All rights reserved.