High adsorption performance for As(Ⅲ) and As(V) onto novel aluminum-enriched biochar derived from abandoned Tetra Paks

摘要

In order to develop promising sorbents for value-added application of solid wastes, low-cost aluminum-enriched biochar was prepared from abandoned Tetra Pak used to hold milks, a paper-polyethylence-Al foil laminated package box, after acid pretreatment and subsequent slow pyrolysis under an oxygen-limited environment at 600 °C. The basic physicochemical properties of the resultant biochar were characterized and the sorption performance of aqueous As(III) and As(V) was investigated via batch and column sorption experiments. Carbon (49.1%), Ca (7.41%) and Al (13.5%) were the most abundant elements in the resultant biochar; and the specific surface area and the pH value at the point of zero charge (pHPZC) were 174 m2 g−1and 9.3, respectively. Batch sorption showed excellent sorption performance for both As(III) (24.2 mg g−1) and As(V) (33.2 mg g−1) and experimental data were fitted well with Langmuir model for the sorption isotherms and pseudo-second order kinetic model for the sorption kinetics. The residual concentrations of As(V) after sorption were below the limited value of arsenic in WHOGuidelines for Drinking water Quality(0.01 mg L−1) even if coexistence of PO43−. Column sorption confirmed the high sorption performance for As(III) and As(V). So the slow pyrolysis of abandoned Tetra Paks as low-cost and value-added sorbents is a sustainable strategy for solid waste disposal and wastewater treatment.