Enhancing Smm Properties Via Axial Distortion Of (mn~Ⅲ)_3 Clusters

摘要

Replacement of carboxylate and solvent with facially capping tripodal ligands enhances the single-molecule magnet (SMM) properties of [(Mn~Ⅲ)_3] triangles.rnStudies of the magnetic behaviour of molecular cluster compounds have seen a resurgence in recent years because such species are the gateway for discovering fascinating new physics. The emergence of molecular nanomagnets in proposed applications as diverse as information storage, molecular spintronics, quantum computation, magnetic refrigeration and MRI has seen synthetic chemists, physicists, theoreticians and materials scientists working in tandem to create, understand and design molecules with specific properties.