Reversible RS-NO bond cleavage and formation at copper(I) thiolates

Marie M. Melzer; Ercheng Li; Timothy H. Warren

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Reversible RS-NO bond cleavage and formation at copper(I) thiolates

机译：硫醇铜（I）上可逆的RS-NO键断裂和形成

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Two coordinate copper(I) thiolates IPrCu-SR undergo rapid, reversible transnitrosation with S-nitrosothioIs RSNOs without catalyzing the loss of NO_(gas) from these biological carriers of NO.

机译：两个配位的硫醇铜（I）IPrCu-SR与S-亚硝基硫醇的RSNO进行快速可逆的亚硝化反应，而没有催化这些生物NO载体中NO_（气体）的损失。

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《Chemical Communications》 |2009年第39期|5847-5849|共3页
作者
Marie M. Melzer; Ercheng Li; Timothy H. Warren;
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Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227, USA;

Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227, USA;

Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227, USA;

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Reversible RS-NO bond cleavage and formation at copper(I) thiolates

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