Boryl ligands and their roles in metal-catalysed borylation reactions

Li Dang; Zhenyang Lin; Todd B. Marder

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Boryl ligands and their roles in metal-catalysed borylation reactions

机译：硼基配体及其在金属催化的硼化反应中的作用

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In this feature article, we discuss selected recent aspects of metal boryl (M-BR_2) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong σ-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.

机译：在这篇专题文章中，我们讨论了金属硼烷基（M-BR_2）化学的某些最新方面，尤其涉及后期和过渡金属硼烷基络合物在各种催化过程中的作用。突出了硼基配体的异常强的σ-供体性质及其相关的亲核行为。

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《Chemical Communications》 |2009年第27期|3987-3995|共9页
作者
Li Dang; Zhenyang Lin; Todd B. Marder;
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Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong;

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong;

Department of Chemistry, Durham University, South Road, Durham, UK DH1 3LE;

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1. DFT studies of beta-boryl elimination processes: Potential role in catalyzed borylation reactions of alkenes [J] . Lam KC, Lin ZY, Marder TB Organometallics . 2007,第13期

机译：DFT研究β-硼基消除过程：烯烃催化的硼化反应中的潜在作用
2. Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C(sp~2)-H Borylation of Diarylmethylamines [J] . Zou Xiaoliang, Zhao Haonan, Li Yinwu, Journal of the American Chemical Society . 2019,第13期

机译：手性双齿硼烷基配体使铱催化二芳基甲胺的不对称C（sp〜2）-H硼化反应
3. Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp~3)-H Borylation of Cyclopropanes [J] . Shi Yongjia, Gao Qian, Xu Senmiao Journal of the American Chemical Society . 2019,第27期

机译：手性双齿硼烷基配体使铱催化环丙烷的对映选择性C（sp〜3）-H硼化
4. Role of the Silver Salt in the Stereoselective Ligand Exchange Reaction of the Diiodoiridium(III)Complex Bearing the Cp'-P Ligand with Triphenylphosphine in the Presence of AgOTf [C] . Takahiro Goi, Yasutaka Kataoka, Kazushi Mashima, Symposium on Organometallic Chemistry . 2003

机译：银盐在二碘辛（III）复合物的立体选择性配体交换反应中的作用，其含有三苯基膦的Cp'-P配体在agotf存在下
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Correction: Ding S. et al. NNB-Type Tridentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C–H Borylation. Molecules 2019 24 1434 [O] . Siyi Ding, Linghua Wang, Zongcheng Miao, 2019

机译：校正：DingS.等。 NNB型三齿硼基配体使高活性铱催化剂能够进行C–H硼化反应。分子2019241434
7. DFT Studies of b-Boryl Elimination Processes: Potential Role in Catalyzed Borylation Reactions of Alkenes [O] . -1

机译：B-Boryl消除过程的DFT研究：含烯烃催化促进反应中的潜在作用

Boryl ligands and their roles in metal-catalysed borylation reactions

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