Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes

Xiaoyu Yan; Yiqing Zhou; Chanjuan Xi

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Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes

机译：炔基锆酸酯对烯丙基溴的反应活性：β-烯丙基-氧化锆环戊二烯的选择性形成

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摘要

Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.

机译：炔基锆酸酯与烯丙基溴的反应提供了在独特的反应位点具有高选择性的β-烯丙基-氧化锆环戊二烯。

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《Chemical Communications》 |2010年第41期|p.7801-7803|共3页
作者
Xiaoyu Yan; Yiqing Zhou; Chanjuan Xi;
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Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry,Tsinghua University, Beijing 100084, China;

rnKey Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry,Tsinghua University, Beijing 100084, China;

rnKey Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry,Tsinghua University, Beijing 100084, China State Key Laboratory of Elemento-Organic Chemistry,Nankai University, Tianjin 300071, China;

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Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes

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