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Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

机译:铱C-H硼化中的电子效应:不受约束的底物和硼基配体取代基变化的见解

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摘要

Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state.
机译:实验和理论支持一种C-H硼化的模型,该模型在过渡态中存在明显的质子转移特征。

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  • 来源
    《Chemical Communications》 |2010年第41期|p.7724-7726|共3页
  • 作者单位

    Department of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

    rnDepartment of Chemistry, Texas A&M University, P.O. Box 30012,College Station, Texas 77842, USA;

    rnDepartment of Chemistry, Michigan State University, East Lansing,Michigan 48824-1322, USA;

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