Bronsted acid sites of zeolitic strength in amorphous silica-alumina

摘要

The most acidic OH groups in silica-aluminas (zeolites, clays, amorphous silica-aluminas) can be made to react selectively with C_6,D_6 to give acidic OD groups; quantification by IR spectroscopy shows that differences in the overall Bronsted acidity of aluminosilicates are dominated by differences in the density of sites of similar acid strength.