Photochirogenesis in chiral ionic liquid: enantiodifferentiating [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid in (R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide

Gaku Fukuhara; Cinzia Chiappe; Andrea Mele; Bernardo Melai; Fabio Bellina; Yoshihisa Inoue

首页> 外文期刊>Chemical Communications >Photochirogenesis in chiral ionic liquid: enantiodifferentiating [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid in (R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide

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Photochirogenesis in chiral ionic liquid: enantiodifferentiating [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid in (R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide

机译：手性离子液体中的光化学发生：（R）-1-甲基-3-（2,3-二羟丙基）咪唑鎓双嘧啶化物中2-蒽羧酸的对映增差[4 + 4]光环二聚化

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Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid and its alkali metal salts performed in a chiral ionic liquid gave chiral cyclodimers in good enantiomeric excesses of up to 41%, which is the highest ever reported for a photochirogenic reaction in chiral media.

机译：在手性离子液体中进行2-蒽羧酸及其碱金属盐的对映增光性二环二聚反应，得到的手性环二聚体的对映体过量高达41％，这是有报道的手性介质中光致化学反应最高的。

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《Chemical Communications》 |2010年第20期|P.3472-3474|共3页
作者
Gaku Fukuhara; Cinzia Chiappe; Andrea Mele; Bernardo Melai; Fabio Bellina; Yoshihisa Inoue;
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Department of Applied Chemistry, Osaka University,2-1 Yamada-oka, Suita 565-0871, Japan;

rnDipartimento di Chimica e Chimica Industriale, Universitd di Pisa,via Risorgimento 35, 56126 Pisa, Italy;

rnDipartimento di Chimica, Materiali e Ingegneria Chimica 'G. Matta', Politecnico di Milano, via Mancinelli 7, 20131 Milano,Italy;

rnDipartimento di Chimica e Chimica Industriale, Universitd di Pisa,via Risorgimento 35, 56126 Pisa, Italy;

rnDipartimento di Chimica e Chimica Industriale, Universitd di Pisa,via Risorgimento 35, 56126 Pisa, Italy;

rnDepartment of Applied Chemistry, Osaka University,2-1 Yamada-oka, Suita 565-0871, Japan;

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1. Chiral ionic liquid-mediated photochirogenesis. Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid [J] . Gaku Fukuhara, Takahiro Okazaki, Marco Lessi, Organic & biomolecular chemistry . 2011,第20期

机译：手性离子液体介导的光化学发生。对映异构化2-蒽羧酸的光环二聚
2. Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid using a chiral N-(2-hydroxymethyl-4-pyrrolidinyl)benzamide template [J] . Mizoguchi J, Kawanami Y, Wada T, Organic letters . 2006,第26期

机译：使用手性N-（2-羟甲基-4-吡咯烷基）苯甲酰胺模板对映增强2-蒽光环二聚光
3. Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid using a chiral N-(2-hydroxymethyl-4-pyrrolidinyl)benzamide template [J] . Mizoguchi J, Kawanami Y, Wada T, Organic letters . 2006,第26期

机译：使用手性N-（2-羟甲基-4-吡咯烷基）苯甲酰胺模板对映增强2-蒽的光环二聚化
4. ELECTRODEPOSITION OF ALUMINUM IN 1-METHYL-3- HEXYL IMIDAZOLIUM CHLORIDE IONIC LIQUID AT LOW TEMPERATURES [C] . Ramana.G.Reddy, Venkat Kamavaram Meeting of the Electrochemical Society . 2002

机译：低温下1-甲基-3-己基咪唑鎓氯化铝离子液体的电沉积
5. Syntheses of PEG/alkyl-based imidazolium/pyridinium ionic liquids and applications on H2S absorption and syntheses of polysulfone based functionalized imidazolium ionic polymers and applications on gas separation. [D] . Zhang, Chengda. 2015

机译：PEG /烷基咪唑/吡啶离子液体的合成及其在H2S吸收中的应用和聚砜基官能化咪唑离子聚合物的合成及其在气体分离中的应用。
6. The Effect of the Methylation and N-H Acidic Group on the Physicochemical Properties of Imidazolium-Based Ionic Liquids [O] . Ana S.M.C. Rodrigues, Marisa A. A. Rocha, Hugo F. D. Almeida, -1

机译：甲基化和N-H酸性基团对基于咪唑鎓离子液体的理化性质的影响
7. Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylic Acid Using a Chiral N-(2-Hydroxymethyl-4-pyrrodidinyl)benzamide Template [O] . -1

机译：使用手性N-（2-羟甲基-4-吡啶基）苯甲酰胺模板对2-蒽羧酸的光粘接过化的光粘接性

Photochirogenesis in chiral ionic liquid: enantiodifferentiating [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid in (R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide

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