Resorcin[4]arene cavitand with l,3,2-benzodiazaborolyl walls as a fluorescence receptor for ammonium cations

Yuji Kubo; Kazusa Tsuruzoe; Sachiko Okuyama; Ryuhei Nishiyabu; Takashi Fujihara

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Resorcin[4]arene cavitand with l,3,2-benzodiazaborolyl walls as a fluorescence receptor for ammonium cations

机译：具有1,3,2-苯并二氮杂硼烯丙基壁的间苯二酚[4]芳烃cavitand作为铵阳离子的荧光受体

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摘要

Resorcin[4]arene cavitand 1 with 1,3,2-benzodiazaborolyl walls was newly synthesized. It showed a large blue shift in the fluorescence spectra upon selective complexation with alkyl-trimethylammonium salts in CH_2Cl_2-DMSO (9:1 v/v); this shift was detectable with the naked eye.

机译：合成了具有1,3,2-苯并二氮杂硼烯丙基壁的间苯二酚[4]芳烃cavitand 1。与烷基三甲基铵盐在CH_2Cl_2-DMSO（9：1 v / v）中进行选择性络合后，荧光光谱显示出较大的蓝移。用肉眼可以察觉到这种变化。

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《Chemical Communications》 |2010年第20期|P.3604-3606|共3页
作者
Yuji Kubo; Kazusa Tsuruzoe; Sachiko Okuyama; Ryuhei Nishiyabu; Takashi Fujihara;
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Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University,1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan;

Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University,1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan;

rnDepartment of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University,1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan;

rnDepartment of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University,1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan;

rnMolecular Analysis and Life Science Center, Saitama University,255 Shimo-ohkubo, Sakura-ku, Saitama 338-8570, Japan;

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5. Synthesis and applications of novel resorcin[4]arene cavitands [D] . Leaym, Xiaoxuan 2008

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7. Hybrid Cavitand-Resorcin4arene Receptor for the Selective Binding of Choline and Related Compounds in Protic Media [O] . -1

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Resorcin[4]arene cavitand with l,3,2-benzodiazaborolyl walls as a fluorescence receptor for ammonium cations

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