Chiral binaphthylbisbipyridine-based copper(Ⅰ) coordination polymer gels as supramolecular catalysts

摘要

A novel class of chiral coordination polymer organogels, with multi-stimuli responsive properties and suitable for use as catalysts in 1,3-dipolar Huisgen cycloaddition reaction, are reported. Recently, studies on metallogels have received much interest from chemists because the presence of the metal ions may endow the gel unusual functionalities such as spectroscopic, magnetic, redox and catalytic properties.