Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

Samir Barman; Hiroyasu Furukawa; Olivier Blacque; Koushik Venkatesan; Omar M. Yaghi; Guo-Xin Jin; Heinz Berke

首页> 外文期刊>Chemical Communications >Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

【24h】

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

机译：通过原位生成的配体缺陷型金属-接头配合物将金属活性位点引入MOF

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

机译：合成并表征了两个新颖的3D MOF，即MOF-647A和MOF-648（以前未知的三结四联网络），它们由Cu离子和吡唑-3,5-二羧酸盐组成。通过利用原位生成的金属连接物复合物作为构建MOF-648的前体，研究了在MOF中引入开放金属位点的策略。

著录项

来源
《Chemical Communications》 |2011年第43期|p.11882-11884|共3页
作者
Samir Barman; Hiroyasu Furukawa; Olivier Blacque; Koushik Venkatesan; Omar M. Yaghi; Guo-Xin Jin; Heinz Berke;
展开▼
作者单位

Department of Inorganic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland;

Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California-Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA;

Department of Inorganic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland;

Department of Inorganic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland;

Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California-Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA;

Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, 200433, Shanghai, P. R. China;

Department of Inorganic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057, Zurich, Switzerland;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Formation of C-C and C-0 bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands [J] . Tao Lei, Qian Gao, Wen-Qian Chen Inorganic Chemistry Communications . 2013,第Null期

机译：通过溶剂热原位金属-配体反应形成C-C和C-0键：原位生成的多齿席夫碱配体支撑的两种新型镍（II）配合物的合成和晶体结构
2. Highly active and stereoselective olefin polymerization catalysts generated by the transfer-epimetallation of olefins or acetylenes with dialkyltitanium(IV) complexes: Three-membered metallocycles as active catalyst sites [J] . Eisch JJ, Gitua JN, Otieno PO, Macromolecular symposia . 2004,第0期

机译：通过烯烃或乙炔与二烷基钛（IV）配合物的转移-表金属化反应生成的高活性和立体选择性烯烃聚合催化剂：三元金属环作为活性催化剂位点
3. Cobalt Metal-Organic Frameworks Incorporating Redox-Active Tetrathiafulvalene Ligand: Structures and Effect of LLCT within the MOF on Photoelectrochemical Properties [J] . Jiang Miao, Weng Yi-Gang, Zhou Zi-Yao, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第15期

机译：掺入氧化还原活性左右富含瓦丙烯配体的钴金属 - 有机框架：光电化学性质MOF内L1CT的结构和效果
4. Transition Metal Complexes Incorporating with Unsymmetrical N2O_(2-)Donor Schiff Base Ligand:Microwave-Assisted Synthesis,Spectroscopic,Thermal,and Biological Aspects [C] . Amit Ramdasji Yaul, Sarika Ramdasji Yaul, Jagannath Tulshiram Makode International Conference on Advances in Materials Science . 2020

机译：过渡金属配合物与非对称N2O_（2-）供体席夫碱配体：微波辅助合成，光谱，热和生物方面
5. New Donor-Acceptor Charge-Transfer Complexes of Transition Metals Incorporating Redox-Active Ligands. [D] . Seraya, Elaine Victoria. 2016

机译：包含氧化还原活性配体的过渡金属的新的供体-受体电荷转移络合物。
6. Incorporation of Thiolate Donation Using 22′-Dithiodibenzaldehyde: Complexes of a Pentadentate N2S3 Ligand With Relevance to the Active Site of Co Nitrile Hydratase [O] . Bradley W. Smucker, Michael J. VanStipdonk, David M. Eichhorn -1

机译：硫醇盐捐赠使用22-二硫代二苯甲醛的掺入：五齿N2S3配体与钴腈水合酶活性位点的复合物
7. Incorporation of thiolate donation using 2,2'-dithiodibenzaldehyde: complexes of a pentadentate N2S3 ligand with relevance to the active site of Co nitrile hydratase [O] . Smucker, Bradley W., Van Stipdonk, Michael J., Eichhorn, David M. 2007

机译：使用2,2'-二硫代二苯甲醛掺入硫醇盐捐赠物：五齿N2S3配体的复合物，与Co腈水合酶的活性位点相关

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

摘要

著录项

相似文献

相关主题

期刊订阅